JEE Main 20204 SeptemberMorning Shift
- Exam
- JEE Main
- Year
- 2020
- Date
- 4 September
- Shift
- Morning Shift
- Subject
- Chemistry
- Chapter
- Carboxylic Acid Derivatives
JEE Main 2020 · 4 September · Morning Shift · Chemistry · Carboxylic Acid Derivatives
[P] on treatment with Br _ 2 / FeBr _ 3 in CCl _ 4 produced a...
on treatment with produced a single isomer wile heating \left[P\right] is:![[P] on treatment with Br _ 2 / FeBr _ 3 in CCl _ 4 produced a single isomer C _ 8 H _ 7 O _ 2 Br wile heating [P] with](/api/proxy-image?clean=1&b=aHR0cHM6Ly9jZG4tcXVlc3Rpb24tcG9vbC5nZXRtYXJrcy5hcHAvcHlxL2plZV9tYWluLzM5NGJiYmZkLWNlYjYtNDRjYS1hMjEzLTIzMzViZTcwYWJjYi1pbWFnZS5wbmc)
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![[P] on treatment with Br _ 2 / FeBr _ 3 in CCl _ 4 produced a single isomer C _ 8 H _ 7 O _ 2 Br wile heating [P] with](/api/proxy-image?clean=1&url=https%3A%2F%2Ffirebasestorage.googleapis.com%2Fv0%2Fb%2Fquantrexacademy-app.firebasestorage.app%2Fo%2Fquestions%252Ffigs%252Fpyq%252Fjee_main%252F2a166754-69a5-4828-885a-a4c08db852ef-image.png%3Falt%3Dmedia)
![[P] on treatment with Br _ 2 / FeBr _ 3 in CCl _ 4 produced a single isomer C _ 8 H _ 7 O _ 2 Br wile heating [P] with](/api/proxy-image?clean=1&url=https%3A%2F%2Ffirebasestorage.googleapis.com%2Fv0%2Fb%2Fquantrexacademy-app.firebasestorage.app%2Fo%2Fquestions%252Ffigs%252Fpyq%252Fjee_main%252F5d478922-fda9-4181-a1cd-ffff32e4ece3-image.png%3Falt%3Dmedia)
![[P] on treatment with Br _ 2 / FeBr _ 3 in CCl _ 4 produced a single isomer C _ 8 H _ 7 O _ 2 Br wile heating [P] with](/api/proxy-image?clean=1&url=https%3A%2F%2Ffirebasestorage.googleapis.com%2Fv0%2Fb%2Fquantrexacademy-app.firebasestorage.app%2Fo%2Fquestions%252Ffigs%252Fpyq%252Fjee_main%252F0fbe9d4c-9cfd-4267-a16f-cf1e5e45d785-image.png%3Falt%3Dmedia)
![[P] on treatment with Br _ 2 / FeBr _ 3 in CCl _ 4 produced a single isomer C _ 8 H _ 7 O _ 2 Br wile heating [P] with](/api/proxy-image?clean=1&url=https%3A%2F%2Ffirebasestorage.googleapis.com%2Fv0%2Fb%2Fquantrexacademy-app.firebasestorage.app%2Fo%2Fquestions%252Ffigs%252Fpyq%252Fjee_main%252Feeed523f-8ce7-4824-922a-eacc9a8c74c2-image.png%3Falt%3Dmedia)
![[P] on treatment with Br _ 2 / FeBr _ 3 in CCl _ 4 produced a single isomer C _ 8 H _ 7 O _ 2 Br wile heating [P] with](/api/proxy-image?clean=1&url=https%3A%2F%2Ffirebasestorage.googleapis.com%2Fv0%2Fb%2Fquantrexacademy-app.firebasestorage.app%2Fo%2Fquestions%252Ffigs%252Fpyq%252Fjee_main%252F2a166754-69a5-4828-885a-a4c08db852ef-image.png%3Falt%3Dmedia)
![[P] on treatment with Br _ 2 / FeBr _ 3 in CCl _ 4 produced a single isomer C _ 8 H _ 7 O _ 2 Br wile heating [P] with](/api/proxy-image?clean=1&url=https%3A%2F%2Ffirebasestorage.googleapis.com%2Fv0%2Fb%2Fquantrexacademy-app.firebasestorage.app%2Fo%2Fquestions%252Ffigs%252Fpyq%252Fjee_main%252F5d478922-fda9-4181-a1cd-ffff32e4ece3-image.png%3Falt%3Dmedia)
![[P] on treatment with Br _ 2 / FeBr _ 3 in CCl _ 4 produced a single isomer C _ 8 H _ 7 O _ 2 Br wile heating [P] with](/api/proxy-image?clean=1&url=https%3A%2F%2Ffirebasestorage.googleapis.com%2Fv0%2Fb%2Fquantrexacademy-app.firebasestorage.app%2Fo%2Fquestions%252Ffigs%252Fpyq%252Fjee_main%252F0fbe9d4c-9cfd-4267-a16f-cf1e5e45d785-image.png%3Falt%3Dmedia)
Options
- A

- B

- C

- D

Correct answer
A. 
Step-by-step solution
Isomer on heating with sodalime gives toluene,hence it is an acid.Moreover since it has Degree of unsaturation 5 therefore it is an aromatic carboxylic acid.Since Carboxylic acid on heating gives toluene ,therefore it is having group attached to the benzene ring.
Now it forms single isomer on halogenation, therefore group must be attached at para position with respect to group.
Hence correct option is 1.