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JEE Main 20265 AprilMorning Shift
Exam
JEE Main
Year
2026
Date
5 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

JEE Main 2026 · 5 April · Morning Shift · Chemistry · Chemical Bonding and Molecular Structure

Consider the following species: BrF _5 , XeF _5^- , BF _4^- , ICl...

Consider the following species:
BrF5_5, XeF5−_5^-, BF4−_4^-, ICl4−_4^-, XeF4_4, SF4_4, NH4+_4^+, ClF3_3, XeF2_2, ICl2−_2^-
Number of species having sp3^3d hybridized central atom is __________.

Correct answer

0

Step-by-step solution

The steric number HH is calculated as H=12(V+M−C+A)H = \dfrac{1}{2}(V + M - C + A), where VV is the number of valence electrons on the central atom, MM is the number of monovalent atoms, CC is the cationic charge, and AA is the anionic charge.

For sp3dsp^3d hybridization, H=5H = 5.

BrF5_5: H=12(7+5)=6H = \dfrac{1}{2}(7 + 5) = 6 (sp3d2sp^3d^2)

XeF5−_5^-: H=12(8+5+1)=7H = \dfrac{1}{2}(8 + 5 + 1) = 7 (sp3d3sp^3d^3)

BF4−_4^-: H=12(3+4+1)=4H = \dfrac{1}{2}(3 + 4 + 1) = 4 (sp3sp^3)

ICl4−_4^-: H=12(7+4+1)=6H = \dfrac{1}{2}(7 + 4 + 1) = 6 (sp3d2sp^3d^2)

XeF4_4: H=12(8+4)=6H = \dfrac{1}{2}(8 + 4) = 6 (sp3d2sp^3d^2)

SF4_4: H=12(6+4)=5H = \dfrac{1}{2}(6 + 4) = 5 (sp3dsp^3d)

NH4+_4^+: H=12(5+4−1)=4H = \dfrac{1}{2}(5 + 4 - 1) = 4 (sp3sp^3)

ClF3_3: H=12(7+3)=5H = \dfrac{1}{2}(7 + 3) = 5 (sp3dsp^3d)

XeF2_2: H=12(8+2)=5H = \dfrac{1}{2}(8 + 2) = 5 (sp3dsp^3d)

ICl2−_2^-: H=12(7+2+1)=5H = \dfrac{1}{2}(7 + 2 + 1) = 5 (sp3dsp^3d)

The species with sp3dsp^3d hybridization are SF4_4, ClF3_3, XeF2_2, and ICl2−_2^-.

The number of such species is 44.

Answer: 44
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