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JEE Main 20254 AprilEvening Shift
Exam
JEE Main
Year
2025
Date
4 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

JEE Main 2025 · 4 April · Evening Shift · Chemistry · Chemical Bonding and Molecular Structure

Given below are two statements: Statement (I) : for ClF_3 , all...

Given below are two statements:
Statement (I) : for ClF3\mathrm{ClF}_3, all three possible structures may be drawn as follows.
Given below are two statements: Statement (I) : for ClF_3 , all three possible structures may be drawn as follows.
Statement (II) : Structure III is most stable, as the orbitals having the lone pairs are axial, where the ℓp−bp\ell \mathrm{p}-\mathrm{bp} repulsion is minimum.
In the light of the above statements, choose the most appropriate answer from the options given below:

Options

  1. AStatement I is incorrect but statement II is correct.
  2. BStatement I is correct but statement II is incorrect.
  3. CBoth Statement I and statement II are correct.
  4. DBoth Statement I and statement II are incorrect.

Correct answer

B. Statement I is correct but statement II is incorrect.

Step-by-step solution

Statement 1 is correct.
Statement 2 is incorrect since in sp3 d\mathrm{sp}^3 \mathrm{~d} hybridization; lone pair cannot occupy axial position.
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