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JEE Main202431 Jan 2024Morning ShiftChemistryChemical Bonding and Molecular StructureActual

The linear combination of atomic orbitals to form molecular orbitals takes place only when the combining atomic orbitals A. have the same energy B. have the minimum overlap C. have same symmetry about the molecular axis D. have different symmetry about the molecular axis Choose the most appropriate from the options given below:

Options

  1. AA, B, C only
  2. BA and C only
  3. CB, C, D only
  4. DB and D only

Correct answer

B. A and C only

Step-by-step solution

The given conditions should be satisfied by atomic orbitals to form molecular orbitals: (a) The atomic orbital with one electron (completely half filled) can take part in combination or overlapping. (b) During the time of overlap, the combining orbitals must have opposite spins of electrons. (c) The combining atomic orbitals must have the same or nearly the same energy. This means that in a homonuclear molecule, the 1 s-atomic orbital of an atom can combine with the 1 s-atomic orbital of another atom, and not with

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