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JEE Main 202313 AprilEvening Shift
Exam
JEE Main
Year
2023
Date
13 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

JEE Main 2023 · 13 April · Evening Shift · Chemistry · Chemical Bonding and Molecular Structure

Given below are two statements : Statement I : SO _ 2 and H _ 2 O...

Given below are two statements :

Statement I : SO2{SO}_{2} and H2O{H}_{2}O both possess V-shaped structure

Statement II : The bond angle of SO2{SO}_{2} is less than that of H2O{H}_{2}O.

In the light of the above statements, choose the most appropriate answer from the options given below:

Given below are two statements : Statement I : SO _ 2 and H _ 2 O both possess V-shaped structure Statement II : The

Options

  1. ABoth Statement I and Statement II are incorrect
  2. BBoth Statement I and Statement II are correct
  3. CStatement I is incorrect but Statement II is correct
  4. DStatement I is correct but Statement II is incorrect

Correct answer

D. Statement I is correct but Statement II is incorrect

Step-by-step solution

The molecule SO2{SO}_{2} is having two sigma bond pairs and lone pair, hence, it exhibits angular or V-shape structure. The molecule H2O{H}_{2}O is having two sigma bond pairs and a lone pair hence, it exhibits angular or V-shape structure. So, both molecules are having same shape. But double bond-double bond repulsions are greater than single bond repulsions, hence, the bond angle in sulphur dioxide is greater than water.

Given below are two statements : Statement I : SO _ 2 and H _ 2 O both possess V-shaped structure Statement II : The

SO2{SO}_{2} and H2O{H}_{2}O both have V-Shape

Bond angle: SO2>H2O{SO}_{2} > {H}_{2}O

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