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JEE Main 20238 AprilMorning Shift
Exam
JEE Main
Year
2023
Date
8 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

JEE Main 2023 · 8 April · Morning Shift · Chemistry · Chemical Bonding and Molecular Structure

Given below are two statements : One is labelled as AssertionA and...

Given below are two statements : One is labelled as AssertionAAssertionA and the other is labelled as ReasonRReasonR.

AssertionA:AssertionA: Butan–11–ol has higher boiling point than ethoxyethane.

ReasonR:ReasonR: Extensive hydrogen bonding leads to stronger association of molecules.

In the light of the above statements, choose the correct answer from the options given below :

Options

  1. AA is true but R is false
  2. BBoth A and R are true and R is the correct explanation of A
  3. CBoth A and R are true but R is not the correct explanation of A
  4. DA is false but R is true

Correct answer

B. Both A and R are true and R is the correct explanation of A

Step-by-step solution

Butan-11-ol can undergo hydrogen bonding due to the presence of an −OH- OH group, ethoxyethane (also known as diethyl ether) can also participate in hydrogen bonding.

Even though there are no hydrogen atoms directly bonded to a highly electronegative atom (likeF,O,orNF, O, orN) in ethoxyethane, the molecule still has polar C−OC - O bonds that can lead to dipole-dipole interactions with other polar molecules.

Owing to intermolecular hydrogen bonding in butanol, it has higher boiling point than ethoxyethane.

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