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JEE Main 202227 JulyMorning Shift
Exam
JEE Main
Year
2022
Date
27 July
Shift
Morning Shift
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

JEE Main 2022 · 27 July · Morning Shift · Chemistry · Chemical Bonding and Molecular Structure

According to MO theory, number of species/ions from the following...

According to MOMO theory, number of species/ions from the following having identical bond order is____

CN−,NO+,O2,O2+,O22+{CN}^{-}, {NO}^{+}, {O}_{2}, {O}_{2}^{+}, {O}_{2}^{2 +}

Correct answer

0

Step-by-step solution

The bond order of a diatomic species can be calculated using molecular orbital theory as follows,

Bondorder = \dfrac{No . ofBMOelectrons - No . ofABMOelectrons}{2}</p><p>BMO=bondingmolecularorbital</p><p>ABMO=Antibondingmolecularorbital.</p><p>Basedonthetotalnumberelectronsinbondordersaregiveninthefollowingtable.</p><tableborder="1"cellpadding="1"cellspacing="1"style="width:200px;"><tbody><tr><tdstyle="text−align:center;">Numberof</p><p>BMO = bonding molecular orbital</p><p>ABMO = Anti bonding molecular orbital.</p><p>Based on the total number electrons in bond orders are given in the following table.</p><table border="1" cellpadding="1" cellspacing="1" style="width: 200px;"> <tbody> <tr> <td style="text-align: center;">Number of{e}^{-}</td><tdstyle="text−align:center;">Bondorder</td></tr><tr><tdstyle="text−align:center;"></td> <td style="text-align: center;">Bond order</td> </tr> <tr> <td style="text-align: center;">13</td><tdstyle="text−align:center;"></td> <td style="text-align: center;">2 . 5</td></tr><tr><tdstyle="text−align:center;"></td> </tr> <tr> <td style="text-align: center;">14</td><tdstyle="text−align:center;"></td> <td style="text-align: center;">3</td></tr><tr><tdstyle="text−align:center;"></td> </tr> <tr> <td style="text-align: center;">15</td><tdstyle="text−align:center;"></td> <td style="text-align: center;">2 . 5</td></tr><tr><tdstyle="text−align:center;"></td> </tr> <tr> <td style="text-align: center;">16</td><tdstyle="text−align:center;"></td> <td style="text-align: center;">2</td></tr></tbody></table><p></td> </tr> </tbody></table><p>{CN}^{-}, {NO}^{+}and{O}_{2}^{2 +} are having 14 electrons each, hence the bond order is 3.

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