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JEE Main 202126 AugustEvening Shift
Exam
JEE Main
Year
2021
Date
26 August
Shift
Evening Shift
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

JEE Main 2021 · 26 August · Evening Shift · Chemistry · Chemical Bonding and Molecular Structure

The bond order and magnetic behaviour of O _ 2 ^ - ion are,...

The bond order and magnetic behaviour of O2−{O}_{2}^{-} ion are, respectively :

Options

  1. A1.51 . 5 and diamagnetic.
  2. B1.51 . 5 and paramagnetic.
  3. C22 and diamagnetic.
  4. D11 and paramagnetic

Correct answer

B. 1.51 . 5 and paramagnetic.

Step-by-step solution

O2−{O}_{2}^{-}(Total electron = 17 ) { Bond order =1.5= 1 . 5, Paramagnetic }

σ1s2,σ⋆1s2,σ2s2,σ⋆2s2,σ2Pz2,π2Px2=π2Py2,π∗2Px2=π∗2Py1,σ⋆2Pz0\sigma1{s}^{2}, {\sigma}^{⋆}1{s}^{2}, \sigma2{s}^{2}, {\sigma}^{⋆}2{s}^{2}, \sigma2{P}_{z}^{2}, \pi2{P}_{x}^{2} = \pi2{P}_{y}^{2}, {\pi}^{*}2{P}_{x}^{2} = {\pi}^{*}2{P}_{y}^{1}, {\sigma}^{⋆}2{{P}_{z}}^{0}

Number of unpaired electron =1= 1

Bond order =nb−na2=10−72=1.5= \dfrac{{n}_{b} - {n}_{a}}{2} = \dfrac{10 - 7}{2} = 1 . 5

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