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JEE Main 202126 FebruaryEvening Shift
Exam
JEE Main
Year
2021
Date
26 February
Shift
Evening Shift
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

JEE Main 2021 · 26 February · Evening Shift · Chemistry · Chemical Bonding and Molecular Structure

Match List- I with List- II . List- I List- II (Molecule) (Bond...

Match List-II with List-IIII.

List-II List-IIII
(Molecule) (Bond order)
(a) Ne2{Ne}_{2} (i) 11
(b) N2{N}_{2} (ii) 22
(c) F2{F}_{2} (iii) 00
(d) O2{O}_{2} (iv) 33

Choose the correct answer from the options given below:

Options

  1. A(a)→(ii),(b)→(i),(c)→(iv),(d)→(iii)\left(a\right) \to \left(ii\right), \left(b\right) \to \left(i\right), \left(c\right) \to \left(iv\right), \left(d\right) \to \left(iii\right)
  2. B(a)→(iii),(b)→(iv),(c)→(i),(d)→(ii)\left(a\right) \to \left(iii\right), \left(b\right) \to \left(iv\right), \left(c\right) \to \left(i\right), \left(d\right) \to \left(ii\right)
  3. C(a)→(i),(b)→(ii),(c)→(iii),(d)→(iv)\left(a\right) \to \left(i\right), \left(b\right) \to \left(ii\right), \left(c\right) \to \left(iii\right), \left(d\right) \to \left(iv\right)
  4. D(a)→(iv),(b)→(iii),(c)→(ii),(d)→(i)\left(a\right) \to \left(iv\right), \left(b\right) \to \left(iii\right), \left(c\right) \to \left(ii\right), \left(d\right) \to \left(i\right)

Correct answer

B. (a)→(iii),(b)→(iv),(c)→(i),(d)→(ii)\left(a\right) \to \left(iii\right), \left(b\right) \to \left(iv\right), \left(c\right) \to \left(i\right), \left(d\right) \to \left(ii\right)

Step-by-step solution

Bond order = 12\dfrac{1}{2}​ (number of electrons in bonding MO −-number of electrons in anti-bonding MO)

(a) Ne2={Ne}_{2} = Total eΘ=20{e}^{Θ} = 20

B.O. =10−102=0= \dfrac{10 - 10}{2} = 0

(b) N2={N}_{2} = Total e⊝=14{e}^{⊝} = 14

B.O. =10−42=3= \dfrac{10 - 4}{2} = 3

(c) F2={F}_{2} = Total e⊝=18{e}^{⊝} = 18

B.O. =10−82=1= \dfrac{10 - 8}{2} = 1

(d) O2={O}_{2} = Total e⊝=16{e}^{⊝} = 16

B.O. =10−62=2= \dfrac{10 - 6}{2} = 2

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