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In graphite and diamond, the percentage of p-characters of the hybrid orbitals in hybridization respectively, are

Options

  1. A33   and   25
  2. B67   and   75
  3. C50   and   75
  4. D33   and   75

Correct answer

B. 67   and   75

Step-by-step solution

Graphite Diamond sp 2 hybridisation sp 3 hybridisation %  P = 2 3 × 100 = 67 % %  P = 3 4 × 100 = 75 % For sp 2 : % P character P − 1 P = cosθ P − 1 P = cos 120 = − 0 .5 P − 1 = 0 .5 P 1 .5 P = 1 P = 2 3 % P = 2 3 × 100 = 66 .67 % For sp 3 : % P character P − 1 P = cos 109 ' 28 P − 1 P = 0 .33 P − 1 P = 3 4 % P = 75 %

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