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JEE Main2017ChemistryChemical Bonding and Molecular StructureActual

Which of the following species is not paramagnetic?

Options

  1. AC O
  2. BO 2
  3. CB 2
  4. DN O

Correct answer

A. C O

Step-by-step solution

CO has no unpaired electron while other have unpaired electrons so, paramagnetic in nature.(Apply M.O.T) Molecular orbital configuration ⇒ CO  : like N 2   ;  σ 1 s 2 < σ * 1S 2 < σ 2 S 2 < σ * 2 S 2 < π 2 P x 2 = π 2 P y 2 < σ 2 P z 2     ( No unpaired electrons) O 2   : σ 1 S 2 < σ * 1S 2 < σ 2 S 2 < σ * 2 S 2 < σ 2 P z 2 < π 2 P x 2 = π 2

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