JEE Main2015ChemistryChemical Bonding and Molecular StructureActual
After understanding the assertion and reason, choose the correct option. Assertion: In the bonding molecular orbital (MO) of H 2 , electron density is increased between the nuclei. Reason: The bonding MO is ψ A + ψ B , which shows destructive interference of the combining electron waves.
Options
- AAssertion and Reason are correct, but Reason is not the correct explanation for the Assertion.
- BAssertion and Reason are correct and Reason is the correct explanation for the Assertion.
- CAssertion is incorrect, Reason is correct.
- DAssertion is correct, Reason is incorrect.
Correct answer
D. Assertion is correct, Reason is incorrect.
Step-by-step solution
Electron density between nuclei increased during formation of BMO in H 2 . BMO is ψ A + ψ B (Linear combination of Atomtextc orbitals) provides constructive interference. While by distructive interference anti BMO ψ A − ψ B formed.