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JEE Main2014ChemistryChemical Bonding and Molecular StructureActual

Which one of the following properties is not shown by NO ?

Options

  1. AIt is diamagnetic in gaseous state
  2. BIt is a neutral oxide
  3. CIt combines with oxygen to form nitrogen dioxide
  4. DIt's bond order is 2.5

Correct answer

A. It is diamagnetic in gaseous state

Step-by-step solution

As per MOT, electronic configuration of NO is σ 1 s 2 < σ * 1 s 2 < σ 2 s 2 < σ * 2 s 2 < σ 2 p z 2 < π 2 p x 2 = π 2 p y 2 < π * 2 p x 1 = π * 2 p y 0 It is paramagnetic due to π 2 * py 1 (unpaired electron) Bond order of NO ( i . e . O 2 + ) = 10 − 5 2 = 2.5

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