JEE Main2012ChemistryChemical Bonding and Molecular StructureActual
The formation of molecular complex BF ₃- NH ₃ results in a change in hybridization of boron
Options
- Afrom s p^2 to d s p^2
- Bfrom s p^2 to s p^3
- Cfrom s p^3 to s p^2
- Dfrom s p^3 to s p^3 d
Correct answer
B. from s p^2 to s p^3
Step-by-step solution
In~ BF ₃, ~B is s p^2 hybridized with one empty p_ z orbital. The empty p_ z orbital of BF ₃ can be filled by lone pair of molecules such as NH ₃ . When this occurs a tetrahedral molecule or ion is formed which is s p^3 hybridized.