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JEE Main 20231 FebruaryEvening Shift
Exam
JEE Main
Year
2023
Date
1 February
Shift
Evening Shift
Subject
Chemistry
Chapter
Chemical Equilibrium

JEE Main 2023 · 1 February · Evening Shift · Chemistry · Chemical Equilibrium

The effect of addition of helium gas to the following reaction in...

The effect of addition of helium gas to the following reaction in equilibrium state at constant volume, is :
PCI5(g)⇌PCl3(g)+Cl2(g){PCI}_{5} ( g ) ⇌ {PCl}_{3} ( g ) + {Cl}_{2} ( g )

Options

  1. Athe equilibrium will shift in the forward direction and more of Cl2{Cl}_{2} and PCl3{PCl}_{3} gases will be produced.
  2. Bthe equilibrium will go backward due to suppression of dissociation of PCl5{PCl}_{5}.
  3. Chelium will deactivate PCl5{PCl}_{5} and reaction will stop.
  4. Daddition of helium will not affect the equilibrium.

Correct answer

D. addition of helium will not affect the equilibrium.

Step-by-step solution

PCI5(g)⇌PCl3(g)+Cl2(g){PCI}_{5} ( g ) ⇌ {PCl}_{3} ( g ) + {Cl}_{2} ( g )
In the above reaction vessel, when helium(an inert gas) is added following cases can happen for isobaric and isochoric processes respectively:

Case 1 : At constant P - volume will increase so reaction will shift in forward direction then answer will be A

Case 2 : At constant volume no change in active mass so reaction will not shift in any direction then answer will be D.

Thus, at constant volume, addition of helium will not have any impact on the equilibrium.

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