JEE Main 20264 AprilEvening Shift
- Exam
- JEE Main
- Year
- 2026
- Date
- 4 April
- Shift
- Evening Shift
- Subject
- Chemistry
- Chapter
- Chemical Kinetics
JEE Main 2026 · 4 April · Evening Shift · Chemistry · Chemical Kinetics
Consider the given graph showing variation of reactant...
Consider the given graph showing variation of reactant concentration with time.
Three different reactions were started with identical initial concentration of reactants. Which of the following statement is correct?

Three different reactions were started with identical initial concentration of reactants. Which of the following statement is correct?
Options
- AThe order of all the three reactions is same.
- BThe rate constant of reaction is larger than the rate constant of reaction if the order of reaction is same for both.
- CThe SI unit of rate constant of reaction is s.
- DThermal decomposition of HI on gold surface is an example of reaction .
Correct answer
B. The rate constant of reaction is larger than the rate constant of reaction if the order of reaction is same for both.
Step-by-step solution
Analysis of the graph:
The graph shows reactant concentration vs time for three reactions starting from the same initial concentration.
Curve 1 is a straight line with negative slope. For a zero-order reaction, the integrated rate law is , which is a straight line in vs . Hence, reaction is a zero-order reaction.
Curves 2 and 3 are non-linear (exponential-type decays), so they correspond to reactions of order greater than zero (e.g., first or second order).
Evaluating the options:
The order of all three reactions is the same.
Reaction is zero order while reactions and are of higher order, so this statement is incorrect.
The rate constant of reaction is larger than that of reaction , assuming both have the same order.
Assuming both curves and correspond to the same order (say first order), the integrated rate law is . At any given time , the curve for reaction lies below that of reaction , i.e., . Since both start from the same , reaction is decaying faster, which implies a larger rate constant. Hence , and this statement is correct.
The SI unit of the rate constant of reaction is .
For a zero-order reaction, , so the unit of is that of rate, i.e., . The unit corresponds to a first-order reaction, so this statement is incorrect.
Thermal decomposition of on a gold surface is an example of reaction .
The thermal decomposition of on a gold surface is a well-known zero-order reaction, which corresponds to curve , not curve . Hence this statement is incorrect.
Therefore, the correct option is .
The graph shows reactant concentration vs time for three reactions starting from the same initial concentration.
Curve 1 is a straight line with negative slope. For a zero-order reaction, the integrated rate law is , which is a straight line in vs . Hence, reaction is a zero-order reaction.
Curves 2 and 3 are non-linear (exponential-type decays), so they correspond to reactions of order greater than zero (e.g., first or second order).
Evaluating the options:
The order of all three reactions is the same.
Reaction is zero order while reactions and are of higher order, so this statement is incorrect.
The rate constant of reaction is larger than that of reaction , assuming both have the same order.
Assuming both curves and correspond to the same order (say first order), the integrated rate law is . At any given time , the curve for reaction lies below that of reaction , i.e., . Since both start from the same , reaction is decaying faster, which implies a larger rate constant. Hence , and this statement is correct.
The SI unit of the rate constant of reaction is .
For a zero-order reaction, , so the unit of is that of rate, i.e., . The unit corresponds to a first-order reaction, so this statement is incorrect.
Thermal decomposition of on a gold surface is an example of reaction .
The thermal decomposition of on a gold surface is a well-known zero-order reaction, which corresponds to curve , not curve . Hence this statement is incorrect.
Therefore, the correct option is .