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JEE Main 20264 AprilEvening Shift
Exam
JEE Main
Year
2026
Date
4 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Chemical Kinetics

JEE Main 2026 · 4 April · Evening Shift · Chemistry · Chemical Kinetics

Consider the given graph showing variation of reactant...

Consider the given graph showing variation of reactant concentration with time.
Three different reactions were started with identical initial concentration of reactants. Which of the following statement is correct?
Consider the given graph showing variation of reactant concentration with time. Three different reactions were started

Options

  1. AThe order of all the three reactions is same.
  2. BThe rate constant of reaction 33 is larger than the rate constant of reaction 22 if the order of reaction is same for both.
  3. CThe SI unit of rate constant of reaction 11 is s−1^{-1}.
  4. DThermal decomposition of HI on gold surface is an example of reaction 22.

Correct answer

B. The rate constant of reaction 33 is larger than the rate constant of reaction 22 if the order of reaction is same for both.

Step-by-step solution

Analysis of the graph:
The graph shows reactant concentration [R][R] vs time tt for three reactions starting from the same initial concentration.

Curve 1 is a straight line with negative slope. For a zero-order reaction, the integrated rate law is [R]=[R]0−kt[R] = [R]_0 - kt, which is a straight line in [R][R] vs tt. Hence, reaction 11 is a zero-order reaction.

Curves 2 and 3 are non-linear (exponential-type decays), so they correspond to reactions of order greater than zero (e.g., first or second order).

Evaluating the options:

(1)(1) The order of all three reactions is the same.
Reaction 11 is zero order while reactions 22 and 33 are of higher order, so this statement is incorrect.

(2)(2) The rate constant of reaction 33 is larger than that of reaction 22, assuming both have the same order.
Assuming both curves 22 and 33 correspond to the same order (say first order), the integrated rate law is [R]=[R]0e−kt[R] = [R]_0 e^{-kt}. At any given time tt, the curve for reaction 33 lies below that of reaction 22, i.e., [R]3<[R]2[R]_3 < [R]_2. Since both start from the same [R]0[R]_0, reaction 33 is decaying faster, which implies a larger rate constant. Hence k3>k2k_3 > k_2, and this statement is correct.

(3)(3) The SI unit of the rate constant of reaction 11 is s−1\text{s}^{-1}.
For a zero-order reaction, Rate=k[R]0=k\text{Rate} = k[R]^0 = k, so the unit of kk is that of rate, i.e., mol L−1s−1\text{mol L}^{-1}\text{s}^{-1}. The unit s−1\text{s}^{-1} corresponds to a first-order reaction, so this statement is incorrect.

(4)(4) Thermal decomposition of HIHI on a gold surface is an example of reaction 22.
The thermal decomposition of HIHI on a gold surface is a well-known zero-order reaction, which corresponds to curve 11, not curve 22. Hence this statement is incorrect.

Therefore, the correct option is (2)(2).
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