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JEE Main 202118 MarchEvening Shift
Exam
JEE Main
Year
2021
Date
18 March
Shift
Evening Shift
Subject
Chemistry
Chapter
Electrochemistry

JEE Main 2021 · 18 March · Evening Shift · Chemistry · Electrochemistry

The molar conductivity at infinite dilution of barium chloride,...

The molar conductivity at infinite dilution of barium chloride, sulphuric arid and hydrochloric acid are 280,860280, 860 426Scm2mol−1426{Scm}^{2}{mol}^{- 1} respectively. The molar conductivity at infinite dilution of barium sulphate is ___ Scm2mol−1{Scm}^{2}{mol}^{- 1} ( Round off to the Nearest Integer).

Correct answer

0

Step-by-step solution

From Kohlrausch's law

Λm∞(BaSO4)=λm∞(Ba2+)+λm∞(SO42−){Λ}_{m}^{\infty}\left({BaSO}_{4}\right) = {\lambda}_{m}^{\infty}\left({Ba}^{2 +}\right) + {\lambda}_{m}^{\infty}\left({SO}_{4}^{2 -}\right)

Λm∞(BaSO4)=Λm∞(BaCl2)+Λm∞(H2SO4)−2Λm∞(HCl){Λ}_{m}^{\infty}\left({BaSO}_{4}\right) = {Λ}_{m}^{\infty}\left({BaCl}_{2}\right) + {Λ}_{m}^{\infty}\left({H}_{2}{SO}_{4}\right) - 2{Λ}_{m}^{\infty} ( HCl )

=280+860−2(426)= 280 + 860 - 2 ( 426 )

=288Scm2mol−1= 288{Scm}^{2}{mol}^{- 1}

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