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JEE Main 20264 AprilMorning Shift
Exam
JEE Main
Year
2026
Date
4 April
Shift
Morning Shift
Subject
Chemistry
Chapter
General Organic Chemistry

JEE Main 2026 · 4 April · Morning Shift · Chemistry · General Organic Chemistry

2.0 g of a bromo hydrocarbon (X) was subjected to Carius analysis,...

2.02.0 g of a bromo hydrocarbon (X)(X) was subjected to Carius analysis, gave 3.363.36 g of AgBrAgBr. The percentage of carbon in the compound (X)(X) is 26.7%26.7\%. Total number of carbon atoms in the empirical formula for compound (X)(X) is _____. (Given molar mass in g mol−1^{-1} H:11, C:1212, Br:8080, Ag:108108)

Correct answer

0

Step-by-step solution

Mass of AgBrAgBr formed = 3.363.36 g
Molar mass of AgBr=108+80=188AgBr = 108 + 80 = 188 g mol−1^{-1}

Moles of AgBrAgBr formed = 3.36188≈0.01787\dfrac{3.36}{188} \approx 0.01787 mol
Since 11 mole of AgBrAgBr contains 11 mole of BrBr, moles of BrBr in the compound = 0.017870.01787 mol.
Mass of Br=0.01787×80=1.43Br = 0.01787 \times 80 = 1.43 g

Percentage of BrBr in compound (X)=1.432.0×100=71.5%(X) = \dfrac{1.43}{2.0} \times 100 = 71.5\%
Given percentage of C=26.7%C = 26.7\%
Percentage of H=100%−(71.5%+26.7%)=1.8%H = 100\% - (71.5\% + 26.7\%) = 1.8\%

Now, we find the molar ratio of the elements in the compound:
Moles of C=26.712=2.225C = \dfrac{26.7}{12} = 2.225
Moles of H=1.81=1.8H = \dfrac{1.8}{1} = 1.8
Moles of Br=71.580=0.893Br = \dfrac{71.5}{80} = 0.893

Dividing by the smallest value (0.8930.893) to get the simplest ratio:
C:H:Br=2.2250.893:1.80.893:0.8930.893C : H : Br = \dfrac{2.225}{0.893} : \dfrac{1.8}{0.893} : \dfrac{0.893}{0.893}
C:H:Br≈2.5:2:1C : H : Br \approx 2.5 : 2 : 1

Multiplying by 22 to obtain whole numbers, we get the ratio 5:4:25 : 4 : 2.

The empirical formula of the compound is C5H4Br2C_5H_4Br_2.
The total number of carbon atoms in the empirical formula is 55.

Answer: 55
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