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JEE Main 20262 AprilMorning Shift
Exam
JEE Main
Year
2026
Date
2 April
Shift
Morning Shift
Subject
Chemistry
Chapter
General Organic Chemistry

JEE Main 2026 · 2 April · Morning Shift · Chemistry · General Organic Chemistry

In IUPAC nomenclature, the correct order of decreasing priority of...

In IUPAC nomenclature, the correct order of decreasing priority of functional group is :

Options

  1. A−CONH2,>C=O,−CHO,−NH2,−C≡C−-CONH_2, >C=O, -CHO, -NH_2, -C\equiv C-
  2. B−CONH2,−COOCH3,−CHO,−NH2,−OH-CONH_2, -COOCH_3, -CHO, -NH_2, -OH
  3. C−CONH2,−CHO,>C=O,−NH2,−C≡C−-CONH_2, -CHO, >C=O, -NH_2, -C\equiv C-
  4. D−CONH2,−CHO,−CN,−NH2,−C≡C−-CONH_2, -CHO, -CN, -NH_2, -C\equiv C-

Correct answer

C. −CONH2,−CHO,>C=O,−NH2,−C≡C−-CONH_2, -CHO, >C=O, -NH_2, -C\equiv C-

Step-by-step solution

The correct order of decreasing priority for functional groups in IUPAC nomenclature is:

Carboxylic acids (−COOH-COOH) >> Sulphonic acids (−SO3H-SO_3H) >> Esters (−COOR-COOR) >> Acid halides (−COX-COX) >> Amides (−CONH2-CONH_2) >> Nitriles (−CN-CN) >> Aldehydes (−CHO-CHO) >> Ketones (>C=O>C=O) >> Alcohols (−OH-OH) >> Thiols (−SH-SH) >> Amines (−NH2-NH_2) >> Alkynes (−C≡C−-C\equiv C-).

Checking the given options:
Option (A) is incorrect because −CHO-CHO has a higher priority than >C=O>C=O.
Option (B) is incorrect because −COOCH3-COOCH_3 has a higher priority than −CONH2-CONH_2.
Option (C) correctly follows the priority order: −CONH2>−CHO>>C=O>−NH2>−C≡C−-CONH_2 > -CHO > >C=O > -NH_2 > -C\equiv C-.
Option (D) is incorrect because −CN-CN has a higher priority than −CHO-CHO.

Answer: −CONH2,−CHO,>C=O,−NH2,−C≡C−-CONH_2, -CHO, >C=O, -NH_2, -C\equiv C-
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