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JEE Main 202624 JanuaryEvening Shift
Exam
JEE Main
Year
2026
Date
24 January
Shift
Evening Shift
Subject
Chemistry
Chapter
General Organic Chemistry

JEE Main 2026 · 24 January · Evening Shift · Chemistry · General Organic Chemistry

0.25 g of an organic compound " A " containing carbon, hydrogen and...

0.25 g of an organic compound " A " containing carbon, hydrogen and oxygen was analysed using the combustion method. There was an increase in mass of CaCl2\mathrm{CaCl}_{2} tube and potash tube at the end of the experiment. The amount was found to be 0.15 g and 0.1837 g, respectively. The percentage of oxygen in compound A is %. (Nearest integer)
(Given: molar mass in gmol−1H:1,C:12,O:16\mathrm{g} \mathrm{mol}^{-1} \mathrm{H}: 1, \mathrm{C}: 12, \mathrm{O}: 16)

Correct answer

0

Step-by-step solution

In combustion analysis: CaCl₂ tube absorbs H₂O and potash tube absorbs CO₂.
Mass increase of CaCl₂ = 0.15 g gives moles of H₂O = 0.15/18 = 0.00833 mol, so moles of H = 0.01667 mol and mass of H = 0.01667 g.
Mass increase of potash = 0.1837 g gives moles of CO₂ = 0.1837/44 = 0.00417 mol, so moles of C = 0.00417 mol and mass of C = 0.05 g.
Mass of O = 0.25 - 0.05 - 0.01667 = 0.18333 g.
Percentage of O = (0.18333/0.25) × 100 = 73.33% ≈ 73% (nearest integer).
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