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JEE Main 202524 JanuaryEvening Shift
Exam
JEE Main
Year
2025
Date
24 January
Shift
Evening Shift
Subject
Chemistry
Chapter
General Organic Chemistry

JEE Main 2025 · 24 January · Evening Shift · Chemistry · General Organic Chemistry

Identify correct statement/s : (A) -OCH_3 and -NHCOCH_3 are...

Identify correct statement/s : (A) −OCH3-\mathrm{OCH}_3 and −NHCOCH3-\mathrm{NHCOCH}_3 are activating group. (B) -CN and -OH are meta directing group. (C) -CN and −SO3H-\mathrm{SO}_3 \mathrm{H} are meta directing group. (D) Activating groups act as ortho - and para directing groups. (E) Halides are activating groups. Choose the correct answer from the options given below :

Options

  1. A(A) only
  2. B(A), (B) and (E) only
  3. C(A) and (C) only
  4. D(A), (C) and (D) only

Correct answer

D. (A), (C) and (D) only

Step-by-step solution

−OCH3,NHCOCH3-\mathrm{OCH}_3, \mathrm{NHCOCH}_3 and -OH are activating groups because the atom directly bonded to benzene ring activates the ring by +R effect using its lone pair of electrons. Activating groups are ortho- and para directing groups. -CN and −SO3H-\mathrm{SO}_3 \mathrm{H} are deactivating groups because the atom directly bonded to benzene is bonded to more electronegative atom through multiple bonds and they are meta directing groups due to -R effect. Halides are deactivating groups due to -I effect.
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