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JEE Main 202431 JanuaryMorning Shift
Exam
JEE Main
Year
2024
Date
31 January
Shift
Morning Shift
Subject
Chemistry
Chapter
General Organic Chemistry

JEE Main 2024 · 31 January · Morning Shift · Chemistry · General Organic Chemistry

Given below are two statements: Statement I: IUPAC name of HO - CH...

Given below are two statements:

Statement I: IUPAC name of HO−CH2−(CH2)3−CH2−COCH3HO - {CH}_{2} - ( {CH}_{2}{)}_{3} - {CH}_{2} - {COCH}_{3} is 77-hydroxyheptan-22-one.

Statement II: 22-oxoheptan-77-ol is the correct IUPAC name for the above compound.

In the light of the above statements, Choose the most appropriate answer from the options given below:

Options

  1. AStatement I is correct but Statement II is incorrect.
  2. BBoth Statement I and Statement II are incorrect.
  3. CBoth Statement I and Statement II are correct.
  4. DStatement I is incorrect but Statement II is correct.

Correct answer

A. Statement I is correct but Statement II is incorrect.

Step-by-step solution

Rule 1 :- The longest chain in the molecule will be the parent chain. So, the first thing one should do is to find the longest carbon chain in the molecule.

Rule 2 :- Find out all the substituents present on the carbon chain. It can be any- from methyl to any alcohol substituent.

Rule 3 :- Start numbering the parent chain from the end such that the substituent gets the lowest number. This is called the lowest locant rule.

Rule 4 :- If the substituent occurs more than one time, then the prefix di, tri or tetra is being used with the location of the carbon on which it is present.

Rule 5 :- If more than one substituents are present and they are different. So, these will be named in alphabetical order.

In the given compound, hydroxy group is given at position 77, there is keto group at position 22, carbon chain consists of 77 carbon atoms, hence, it is heptane.

77-Hydroxyheptan-22- One is the correct IUPAC name.

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