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JEE Main202225 Jul 2022Evening ShiftChemistryGeneral Organic ChemistryActual

Arrange the following in decreasing acidic strength.

Options

  1. AA > B > C > D
  2. B  B > A > C > D
  3. CD > C > A > B
  4. DD > C > B >   A

Correct answer

A. A > B > C > D

Step-by-step solution

Acidic nature is more, if the stability of the conjugate base is more. Electron withdrawing groups increases the stability. Nitro group at para position shows - M effect and meta position it shows - I effect only. Methoxy group at meta position shows - I effect, but effect is Iess than nitro group. Methoxy group at para position shows + M effect that decreases the acidic nature.

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