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JEE Main
Exam
JEE Main
Subject
Chemistry
Chapter
Carboxylic Acid Derivatives

JEE Main · Chemistry · Carboxylic Acid Derivatives

Which of the following reaction is feasible?

Which of the following reaction is feasible?Which of the following reaction is feasible?Which of the following reaction is feasible?

Options

  1. AWhat is the time period of the given function:sin ωt + 2 ωt + 4 ωt
  2. BH3\mathrm{H}_3\mathrm{CCH}=\mathrm{CHCH}2OH⟶PCCH3CCH=CHCHO_2 \mathrm{OH} \stackrel{\mathrm{PCC}}{\longrightarrow} \mathrm{H}_3 \mathrm{CCH}=\mathrm{CHCHO}
  3. CCH3CH2CH2OHH+KMnO4H3CCH2CHO\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CH}_2 \mathrm{OH} \stackrel{\mathrm{KMnO}_4}{\mathrm{H}^{+}} \mathrm{H}_3 \mathrm{CCH}_2 \mathrm{CHO}
  4. DWhat is the time period of the given function:sin ωt + 2 ωt + 4 ωt

Correct answer

B. H3\mathrm{H}_3\mathrm{CCH}=\mathrm{CHCH}2OH⟶PCCH3CCH=CHCHO_2 \mathrm{OH} \stackrel{\mathrm{PCC}}{\longrightarrow} \mathrm{H}_3 \mathrm{CCH}=\mathrm{CHCHO}

Step-by-step solution

Reaction in (a) is not feasible because replacement of −OH-\mathrm{OH} by −Cl-\mathrm{Cl} is not possible for phenol due to partial C=O\mathrm{C}=\mathrm{O} bond and resonance stabilization. Reaction is (c) is not feasible because KMnO4\mathrm{KMnO}_4 is a strong oxidizing agent and converts −C−OH-\mathrm{C}-\mathrm{OH} to −COOH-\mathrm{COOH}. Reaction in (d) is not feasible because 20%PO420 \% \mathrm{PO}_4 is not a strong enough dehydrating agent and therefore 85% h3PO485 \% \mathrm{~h}_3\mathrm{PO}_4 is used.
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