Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE Main2013ChemistryGeneral Organic ChemistryActual

A solution of ( - ) 1 - chloro - 1 - phenylethane in toluene racemises slowly in the presence of a small amount of SbCl 5 , due to the formation of :

Options

  1. ACarbocation
  2. BFree radical
  3. CCarbanion
  4. DCarbene

Correct answer

A. Carbocation

Step-by-step solution

(-) - 1 - chloro-1-phenylethane is: . With SbCl 5 carbocation is formed. As the carbocation is planar, Cl ⊖ can again attack from both sides giving racemic mixture. (d, l mixture formed)

Practice General Organic Chemistry on Quantrex Academy →

More from General Organic Chemistry

Given below are two statements: Statement I: Vapours of the liquid with higher boiling point condense before vapours of the liquid with lower boiling points in fractional distillat 2026The total number of aromatic compounds/species from the following is 2026Given below are two statements : Statement I : A mixture of C₁₂ H₂₂ O₁₁ (sugar) and NaCl can be separated by dissolving sugar in alcohol, due to differential solubility. Statement 2026Shown below is the structure of methyl acetate with three different , and carbon - oxygen bonds. The correct order of bond lengths of these bonds is : 2026Given below are two statements: Statement I: 2,6 -diethylcyclohexanone and 6 -methyl- 2 -n-propylcyclohexanone are metamers. Statement II: 2,2,6,6 -tetramethylcyclohexanone exhibit 2026Match List-I with List-II. List-I (Purification technique) List-II (Used to separate) A. Simple distillation I. Steam volatile compound B. Fractional distillation II. Two liquids w 2026Identify the correct IUPAC name of hydrocarbon ( x ) containing three primary carbon atoms and with molar mass 72 g mol ⁻¹ . 2026Given below are two statements: Statement I: On the basis of inductive effect, the order of stability of alkyl carbanions is CH ₃^-> CH₃ -CH₂^- > ( CH₃ )₂ CH ^- > ( CH₃ )₃ C ^- . S 2026 Full General Organic Chemistry list All JEE Main PYQs