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99 Percentile Qs Bank for JEE MainChemistryCarboxylic Acid Derivatives

Which is more stable?

Options

  1. AX
  2. BY
  3. CBoth are equally stable
  4. DCan't be predicted

Correct answer

B. Y

Step-by-step solution

In X structure,OH 2 + group is formed which is a good leaving group. Hence, X is highly unstable. In Y structure,resonance is observed and before protonation, 2 resonanting structures are possible which are given below: In carboxylic acid the oxygen attached to carboxyl carbon is more electronegative and withdraws the electrons of bond. Hence, proton gets attached to the negatively charged carbon. This is why Y structure is more stable than X.

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