99 Percentile Qs Bank for JEE MainChemistryThermodynamics (C)
Consider the reversible isothermal expansion of an ideal gas in a closed system at two different temperatures T 1 and T 2   T 1 < T 2 . The correct graphical depiction of the dependence of work done w on the final volume v .
Correct answer
0
Step-by-step solution
Let the gas is expanded from V 1 to V at T 1 and from V 2 to V at T 2 ∴ At T 1 W 1 = n R T 1 ln V V 1 = nRT ℓ nV - ℓ nV 1 Similarly at T 2 W 2 = n R T 2 l n V - l n V 2 ) ∴ W 1 = nRT 1 lnV - nRT 1 lnV 1 W 2 = nRT 2 lnV - nRT 2 lnV 2 Slope of W 2 > Slope of W 1 As n R T 2 > n R T 1   T 2 > T 1 ∴ The intercept of W 2 is more negative than that of W 1 because V 2 > V 1 .