Concepts Of Physics MCQ Edition [Volume 2]
- Exam
- Concepts Of Physics MCQ Edition [Volume 2]
- Subject
- Physics
- Chapter
- Bohr's Model and Physics of the Atom
Concepts Of Physics MCQ Edition [Volume 2] · Physics · Bohr's Model and Physics of the Atom
A spectroscopic instrument is capable of resolving two closely...
A spectroscopic instrument is capable of resolving two closely spaced wavelengths, and , provided that the ratio is smaller than . This instrument is employed to examine the spectral lines of the Balmer series of hydrogen. Approximately how many lines can the instrument resolve?
Options
- A38
- B42
- C39
- D40
Correct answer
A. 38
Step-by-step solution
The wavelength of the lines in the Balmer series is given by the Rydberg formula:
\dfrac{1}{\lambda} = R_H \left(\dfrac{1}{2^2} - \dfrac{1}{n^2} \right)
where
Differentiating both sides with respect to , we get the wavelength difference between adjacent lines for :
\dfrac{\Delta \lambda}{\lambda^2} =\dfrac{2}{n^3}
\dfrac{2 R_H \lambda^2}{n^3}
The resolving power of the instrument is given by:
\dfrac{\lambda}{\Delta \lambda} = \dfrac{n^3}{2 R_H \lambda}
From the Rydberg formula, for large , we can approximate:
\dfrac{1}{\lambda} \approx \dfrac{R_H}{4} \Rightarrow
Substituting this into the resolving power expression:
\dfrac{\lambda}{\Delta \lambda} \approx \dfrac{n^3}{2 \times 4} = \dfrac{n^3}{8}
Given that the instrument can resolve lines if \dfrac{\lambda}{\Delta \lambda} \le, we have:
\dfrac{n^3}{8} \le
The lines in the Balmer series correspond to transitions from .
The total number of lines that can be resolved is:
Answer: 38
\dfrac{1}{\lambda} = R_H \left(\dfrac{1}{2^2} - \dfrac{1}{n^2} \right)
where
Differentiating both sides with respect to , we get the wavelength difference between adjacent lines for :
\dfrac{\Delta \lambda}{\lambda^2} =\dfrac{2}{n^3}
\dfrac{2 R_H \lambda^2}{n^3}
The resolving power of the instrument is given by:
\dfrac{\lambda}{\Delta \lambda} = \dfrac{n^3}{2 R_H \lambda}
From the Rydberg formula, for large , we can approximate:
\dfrac{1}{\lambda} \approx \dfrac{R_H}{4} \Rightarrow
Substituting this into the resolving power expression:
\dfrac{\lambda}{\Delta \lambda} \approx \dfrac{n^3}{2 \times 4} = \dfrac{n^3}{8}
Given that the instrument can resolve lines if \dfrac{\lambda}{\Delta \lambda} \le, we have:
\dfrac{n^3}{8} \le
The lines in the Balmer series correspond to transitions from .
The total number of lines that can be resolved is:
Answer: 38