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Concepts Of Physics MCQ Edition [Volume 2]
Exam
Concepts Of Physics MCQ Edition [Volume 2]
Subject
Physics
Chapter
Bohr's Model and Physics of the Atom

Concepts Of Physics MCQ Edition [Volume 2] · Physics · Bohr's Model and Physics of the Atom

A spectroscopic instrument is capable of resolving two closely...

A spectroscopic instrument is capable of resolving two closely spaced wavelengths, λ\lambda and λ+Δλ\lambda + \Delta\lambda, provided that the ratio λ/Δλ\lambda/\Delta\lambda is smaller than 80008000. This instrument is employed to examine the spectral lines of the Balmer series of hydrogen. Approximately how many lines can the instrument resolve?

Options

  1. A38
  2. B42
  3. C39
  4. D40

Correct answer

A. 38

Step-by-step solution

The wavelength of the lines in the Balmer series is given by the Rydberg formula:

\dfrac{1}{\lambda} = R_H \left(\dfrac{1}{2^2} - \dfrac{1}{n^2} \right)

where n=3,4,5,…n = 3, 4, 5, \dots

Differentiating both sides with respect to nn, we get the wavelength difference between adjacent lines for Δn=1\Delta n = 1:

\dfrac{\Delta \lambda}{\lambda^2} =RHR_H\dfrac{2}{n^3}

Δλ=\Delta \lambda =\dfrac{2 R_H \lambda^2}{n^3}

The resolving power of the instrument is given by:

\dfrac{\lambda}{\Delta \lambda} = \dfrac{n^3}{2 R_H \lambda}

From the Rydberg formula, for large nn, we can approximate:

\dfrac{1}{\lambda} \approx \dfrac{R_H}{4} \RightarrowRHλ≈4R_H \lambda \approx 4

Substituting this into the resolving power expression:

\dfrac{\lambda}{\Delta \lambda} \approx \dfrac{n^3}{2 \times 4} = \dfrac{n^3}{8}

Given that the instrument can resolve lines if \dfrac{\lambda}{\Delta \lambda} \le80008000, we have:

\dfrac{n^3}{8} \le80008000

n3≤64000n^3 \le 64000

n≤40n \le 40

The lines in the Balmer series correspond to transitions from n=3,4,5,…,40n = 3, 4, 5, \dots, 40.

The total number of lines that can be resolved is:

40−3+1=3840 - 3 + 1 = 38

Answer: 38
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