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Concepts Of Physics MCQ Edition [Volume 2]
Exam
Concepts Of Physics MCQ Edition [Volume 2]
Subject
Physics
Chapter
Bohr's Model and Physics of the Atom

Concepts Of Physics MCQ Edition [Volume 2] · Physics · Bohr's Model and Physics of the Atom

Determine the temperature at which the average thermal kinetic...

Determine the temperature at which the average thermal kinetic energy matches the energy required to excite a hydrogen atom from its ground state to the n=3n = 3 state. Hydrogen can subsequently emit red light with a wavelength of 653.1 nm653.1 \text{ nm}. Due to the Maxwellian distribution of speeds, a hydrogen sample emits red light at temperatures significantly lower than the value calculated here. Assume that hydrogen molecules dissociate into atoms.

Options

  1. A1.4×105 K1.4 \times 10^5 \text{ K}
  2. B9.4×104 K9.4 \times 10^4 \text{ K}
  3. C4.7×104 K4.7 \times 10^4 \text{ K}
  4. D5.6×104 K5.6 \times 10^4 \text{ K}

Correct answer

B. 9.4×104 K9.4 \times 10^4 \text{ K}

Step-by-step solution

The energy required to excite a hydrogen atom from the ground state (n=1n=1) to the n=3n=3 state is given by:

ΔE=13.6(112−132) eV\Delta E = 13.6 \left( \dfrac{1}{1^2} - \dfrac{1}{3^2} \right) \text{ eV}

ΔE=13.6×89 eV≈12.09 eV\Delta E = 13.6 \times \dfrac{8}{9} \text{ eV} \approx 12.09 \text{ eV}

Converting this energy into Joules:

ΔE=12.09×1.6×10−19 J=19.34×10−19 J\Delta E = 12.09 \times 1.6 \times 10^{-19} \text{ J} = 19.34 \times 10^{-19} \text{ J}

Since the hydrogen molecules dissociate into atoms, the gas is monatomic. The average thermal kinetic energy of a monatomic gas is:

K=32kBTK = \dfrac{3}{2} k_B T

Equating the average thermal kinetic energy to the excitation energy:

32kBT=ΔE\dfrac{3}{2} k_B T = \Delta E

T=2ΔE3kBT = \dfrac{2 \Delta E}{3 k_B}

Substituting the standard value of the Boltzmann constant (kB=1.38×10−23 J/Kk_B = 1.38 \times 10^{-23} \text{ J/K}):

T=2×19.34×10−193×1.38×10−23T = \dfrac{2 \times 19.34 \times 10^{-19}}{3 \times 1.38 \times 10^{-23}}

T≈9.34×104 KT \approx 9.34 \times 10^4 \text{ K}

The closest value among the given options is 9.4×104 K9.4 \times 10^4 \text{ K}.
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