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Concepts Of Physics MCQ Edition [Volume 2]
Exam
Concepts Of Physics MCQ Edition [Volume 2]
Subject
Physics
Chapter
Bohr's Model and Physics of the Atom

Concepts Of Physics MCQ Edition [Volume 2] · Physics · Bohr's Model and Physics of the Atom

A light beam with wavelengths distributed uniformly between 450 nm...

A light beam with wavelengths distributed uniformly between 450 nm450 \text{ nm} and 550 nm550 \text{ nm} is passed through a sample of hydrogen gas. Which wavelength will exhibit the least intensity in the transmitted beam?

Options

  1. A465 nm465 \text{ nm}
  2. B532 nm532 \text{ nm}
  3. C487 nm487 \text{ nm}
  4. D512 nm512 \text{ nm}

Correct answer

C. 487 nm487 \text{ nm}

Step-by-step solution

The least intensity in the transmitted beam corresponds to the wavelength that is absorbed by the hydrogen gas.

The given wavelength range is 450 nm450 \text{ nm} to 550 nm550 \text{ nm}, which falls in the visible region. Absorption in the visible region corresponds to the Balmer series, where the electron transitions from the n=2n = 2 state to a higher energy level.

The energy of an electron in the nthn^{\text{th}} orbit of a hydrogen atom is given by:

En=−13.6n2 eVE_n = -\dfrac{13.6}{n^2} \text{ eV}

For the n=2n = 2 state, E2=−3.4 eVE_2 = -3.4 \text{ eV}.

For the n=3n = 3 state, E3=−1.51 eVE_3 = -1.51 \text{ eV}. The energy difference is ΔE=3.4−1.51=1.89 eV\Delta E = 3.4 - 1.51 = 1.89 \text{ eV}, which corresponds to λ=12421.89≈657 nm\lambda = \dfrac{1242}{1.89} \approx 657 \text{ nm} (outside the given range).

For the n=4n = 4 state, E4=−0.85 eVE_4 = -0.85 \text{ eV}. The energy difference for the transition from n=2n = 2 to n=4n = 4 is:

ΔE=E4−E2=−0.85−(−3.4)=2.55 eV\Delta E = E_4 - E_2 = -0.85 - (-3.4) = 2.55 \text{ eV}

The corresponding wavelength is given by:

λ=1242 eV nmΔE=12422.55≈487 nm\lambda = \dfrac{1242 \text{ eV nm}}{\Delta E} = \dfrac{1242}{2.55} \approx 487 \text{ nm}

Since 487 nm487 \text{ nm} lies within the given range of 450 nm450 \text{ nm} to 550 nm550 \text{ nm}, this wavelength will be absorbed by the hydrogen gas, resulting in the least intensity in the transmitted beam.
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