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Concepts Of Physics MCQ Edition [Volume 2]
Exam
Concepts Of Physics MCQ Edition [Volume 2]
Subject
Physics
Chapter
Bohr's Model and Physics of the Atom

Concepts Of Physics MCQ Edition [Volume 2] · Physics · Bohr's Model and Physics of the Atom

A parallel beam of light of wavelength 100 nm passes through a...

A parallel beam of light of wavelength 100 nm100 \text{ nm} passes through a sample of atomic hydrogen gas in the ground state. Assume that when a photon supplies a portion of its energy to a hydrogen atom, the remaining energy emerges as another photon travelling in the same direction as the incident photon. A radiation detector is positioned near the gas to detect radiation propagating perpendicular to the incident beam. Find the wavelengths of radiation that the detector might register.

Options

  1. A121 nm121 \text{ nm}, 654 nm654 \text{ nm}
  2. B103 nm103 \text{ nm}, 121 nm121 \text{ nm}, 654 nm654 \text{ nm}
  3. C100 nm100 \text{ nm}, 103 nm103 \text{ nm}, 121 nm121 \text{ nm}
  4. D103 nm103 \text{ nm}, 560 nm560 \text{ nm}, 654 nm654 \text{ nm}

Correct answer

B. 103 nm103 \text{ nm}, 121 nm121 \text{ nm}, 654 nm654 \text{ nm}

Step-by-step solution

The energy of the incident photon is given by:

E=hcλ=1242 eV nm100 nm=12.42 eVE = \dfrac{hc}{\lambda} = \dfrac{1242 \text{ eV nm}}{100 \text{ nm}} = 12.42 \text{ eV}

The energy required to excite a hydrogen atom from the ground state (n=1n=1) to higher energy states is:

ΔE1→2=13.6(1−122)=10.2 eV\Delta E_{1 \rightarrow 2} = 13.6 \left(1 - \dfrac{1}{2^2}\right) = 10.2 \text{ eV}

ΔE1→3=13.6(1−132)=12.09 eV\Delta E_{1 \rightarrow 3} = 13.6 \left(1 - \dfrac{1}{3^2}\right) = 12.09 \text{ eV}

ΔE1→4=13.6(1−142)=12.75 eV\Delta E_{1 \rightarrow 4} = 13.6 \left(1 - \dfrac{1}{4^2}\right) = 12.75 \text{ eV}

Since the incident photon energy (12.42 eV12.42 \text{ eV}) is greater than 12.09 eV12.09 \text{ eV} but less than 12.75 eV12.75 \text{ eV}, the hydrogen atoms can be excited to the n=2n=2 and n=3n=3 states. The remaining energy is carried by photons moving in the forward direction, which are not detected by the perpendicular detector.

The excited atoms will de-excite and emit photons in all directions. The possible emission transitions are 3→13 \rightarrow 1, 2→12 \rightarrow 1, and 3→23 \rightarrow 2.

The wavelengths of the emitted photons are calculated as follows:

For 3→13 \rightarrow 1: λ31=124212.09≈103 nm\lambda_{31} = \dfrac{1242}{12.09} \approx 103 \text{ nm}

For 2→12 \rightarrow 1: λ21=124210.2≈121 nm\lambda_{21} = \dfrac{1242}{10.2} \approx 121 \text{ nm}

For 3→23 \rightarrow 2: λ32=12421.89≈657 nm\lambda_{32} = \dfrac{1242}{1.89} \approx 657 \text{ nm} (closest to 654 nm654 \text{ nm} in the given options)

Therefore, the detector will register wavelengths of 103 nm103 \text{ nm}, 121 nm121 \text{ nm}, and 654 nm654 \text{ nm}.

Answer: 103 nm103 \text{ nm}, 121 nm121 \text{ nm}, 654 nm654 \text{ nm}
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