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Concepts Of Physics MCQ Edition [Volume 2]
Exam
Concepts Of Physics MCQ Edition [Volume 2]
Subject
Physics
Chapter
Bohr's Model and Physics of the Atom

Concepts Of Physics MCQ Edition [Volume 2] · Physics · Bohr's Model and Physics of the Atom

A parallel beam of light of wavelength 100 nm passes through a...

A parallel beam of light of wavelength 100 nm100 \text{ nm} passes through a sample of atomic hydrogen gas in the ground state. Assume that when a photon supplies a portion of its energy to a hydrogen atom, the remaining energy emerges as another photon travelling in the same direction as the incident photon. Disregarding the light emitted by the excited hydrogen atoms in the direction of the incident beam, what wavelengths can be observed in the transmitted beam?

Options

  1. A100 nm100 \text{ nm}, 560 nm560 \text{ nm}, 3880 nm3880 \text{ nm}
  2. B560 nm560 \text{ nm}, 3880 nm3880 \text{ nm}
  3. C100 nm100 \text{ nm}, 121 nm121 \text{ nm}, 103 nm103 \text{ nm}
  4. D100 nm100 \text{ nm}, 654 nm654 \text{ nm}, 3880 nm3880 \text{ nm}

Correct answer

A. 100 nm100 \text{ nm}, 560 nm560 \text{ nm}, 3880 nm3880 \text{ nm}

Step-by-step solution

Energy of the incident photon is given by:

E=hcλ=1240 eV nm100 nm=12.4 eVE = \dfrac{hc}{\lambda} = \dfrac{1240 \text{ eV nm}}{100 \text{ nm}} = 12.4 \text{ eV}

The energy levels of a hydrogen atom are En=−13.6n2 eVE_n = -\dfrac{13.6}{n^2} \text{ eV}.

The energy required to excite a hydrogen atom from the ground state (n=1n=1) to higher states is:
For n=2n=2: ΔE12=13.6(1−14)=10.2 eV\Delta E_{12} = 13.6 \left(1 - \dfrac{1}{4}\right) = 10.2 \text{ eV}
For n=3n=3: ΔE13=13.6(1−19)≈12.08 eV\Delta E_{13} = 13.6 \left(1 - \dfrac{1}{9}\right) \approx 12.08 \text{ eV}
For n=4n=4: ΔE14=13.6(1−116)=12.75 eV\Delta E_{14} = 13.6 \left(1 - \dfrac{1}{16}\right) = 12.75 \text{ eV}

Since the incident photon energy (12.4 eV12.4 \text{ eV}) is less than 12.75 eV12.75 \text{ eV}, it can only excite the atom to n=2n=2 or n=3n=3.

When the atom is excited to n=2n=2, the remaining energy of the photon is:
E2′=12.4−10.2=2.2 eVE_2' = 12.4 - 10.2 = 2.2 \text{ eV}
The wavelength of this transmitted photon is:
λ2′=12402.2≈563 nm≈560 nm\lambda_2' = \dfrac{1240}{2.2} \approx 563 \text{ nm} \approx 560 \text{ nm}

When the atom is excited to n=3n=3, the remaining energy of the photon is:
E3′=12.4−12.08=0.32 eVE_3' = 12.4 - 12.08 = 0.32 \text{ eV}
The wavelength of this transmitted photon is:
λ3′=12400.32=3875 nm≈3880 nm\lambda_3' = \dfrac{1240}{0.32} = 3875 \text{ nm} \approx 3880 \text{ nm}

The unabsorbed incident photons will also pass through the gas without interacting, so the original 100 nm100 \text{ nm} wavelength will still be present in the transmitted beam.

Therefore, the wavelengths observed in the transmitted beam are 100 nm100 \text{ nm}, 560 nm560 \text{ nm}, and 3880 nm3880 \text{ nm}.

Answer: 100 nm100 \text{ nm}, 560 nm560 \text{ nm}, 3880 nm3880 \text{ nm}
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