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Concepts Of Physics MCQ Edition [Volume 2]
Exam
Concepts Of Physics MCQ Edition [Volume 2]
Subject
Physics
Chapter
Specific Heat Capacities of Gases

Concepts Of Physics MCQ Edition [Volume 2] · Physics · Specific Heat Capacities of Gases

Two rigid vessels A and B , each having a volume of 200 cm^3 ,...

Two rigid vessels AA and BB, each having a volume of 200 cm3200 \text{ cm}^3, contain an ideal gas (CV=12.5 J K−1 mol−1C_V = 12.5 \text{ J K}^{-1} \text{ mol}^{-1}). These vessels are connected to a manometer tube containing mercury, as shown in the figure. The temperature is 300 K300 \text{ K} and the pressure in both vessels is 75 cm75 \text{ cm} of mercury. Determine the number of moles of the gas in each vessel. Use the gas constant R=8.3 J K−1 mol−1R = 8.3 \text{ J K}^{-1} \text{ mol}^{-1}.
Two rigid vessels A and B , each having a volume of 200 cm^3 , contain an ideal gas ( C_V = 12.5 J K^ -1 mol^ -1 ).

Options

  1. A0.0160.016
  2. B0.0240.024
  3. C0.0040.004
  4. D0.0080.008

Correct answer

D. 0.0080.008

Step-by-step solution

Given:
Volume of each vessel, V=200 cm3=200×10−6 m3V = 200 \text{ cm}^3 = 200 \times 10^{-6} \text{ m}^3
Temperature, T=300 KT = 300 \text{ K}
Pressure, P=75 cm of Hg=0.75 m of HgP = 75 \text{ cm of Hg} = 0.75 \text{ m of Hg}
Gas constant, R=8.3 J K−1 mol−1R = 8.3 \text{ J K}^{-1} \text{ mol}^{-1}

First, we convert the pressure into SI units (Pascals):
P=ρghP = \rho g h
Using density of mercury ρ=13600 kg m−3\rho = 13600 \text{ kg m}^{-3} and g=9.8 m s−2g = 9.8 \text{ m s}^{-2}:
P=13600×9.8×0.75=99960 PaP = 13600 \times 9.8 \times 0.75 = 99960 \text{ Pa}

Using the ideal gas equation, PV=nRTPV = nRT, we can find the number of moles nn in each vessel:
n=PVRTn = \dfrac{PV}{RT}

Substituting the values:
n=99960×200×10−68.3×300n = \dfrac{99960 \times 200 \times 10^{-6}}{8.3 \times 300}

n=19.9922490≈0.008 moln = \dfrac{19.992}{2490} \approx 0.008 \text{ mol}

The number of moles of the gas in each vessel is 0.0080.008.
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