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JEE Main 20231 FebruaryEvening Shift
Exam
JEE Main
Year
2023
Date
1 February
Shift
Evening Shift
Subject
Chemistry
Chapter
Hydrogen

JEE Main 2023 · 1 February · Evening Shift · Chemistry · Hydrogen

O - O bond length in H _ 2 O _ 2 is X _ ¯ than the O - O bond...

O−OO - O bond length in H2O2{H}_{2}{O}_{2} is X¯\mathop{X}_{¯} than the O−OO - O bond length in F2O2{F}_{2}{O}_{2}. The O−HO - H bond length in H2O2{H}_{2}{O}_{2} is Y¯\mathop{Y}_{¯} than that of the O−FO - F bond in F2O2{F}_{2}{O}_{2}. Choose the correct option for X¯\mathop{X}_{¯} and Y¯\mathop{Y}_{¯} from the given below.

O - O bond length in H _ 2 O _ 2 is X _ ¯ than the O - O bond length in F _ 2 O _ 2 . The O - H bond length in H _ 2 O

Options

  1. AXX- shorter, Y−Y - shorter
  2. BXX-shorter, YY-longer
  3. CXX-longer, YY-longer
  4. DXX-longer, YY - shorter

Correct answer

D. XX-longer, YY - shorter

Step-by-step solution

According to bent rule more electronegative atom occupy less s-character so bond length increases. O−HO - H bond will be short than O−FO - F bond due to small size of HH than FF. Correspondingly, O−OO - O bond in hydrogen peroxide will be shorter than that of O2F2{O}_{2}{F}_{2}. Corresponding structures are:
O - O bond length in H _ 2 O _ 2 is X _ ¯ than the O - O bond length in F _ 2 O _ 2 . The O - H bond length in H _ 2 O
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