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JEE Main 202623 JanuaryEvening Shift
Exam
JEE Main
Year
2026
Date
23 January
Shift
Evening Shift
Subject
Chemistry
Chapter
p Block Elements (Group 13 & 14)

JEE Main 2026 · 23 January · Evening Shift · Chemistry · p Block Elements (Group 13 & 14)

It is noticed that Pb^ 2+ is more stable than Pb^ 4+ but Sn^ 2+ is...

It is noticed that Pb2+\mathrm{Pb}^{2+} is more stable than Pb4+\mathrm{Pb}^{4+} but Sn2+\mathrm{Sn}^{2+} is less stable than Sn4+\mathrm{Sn}^{4+}. Observe the following reactions.
PbO2+Pb→2PbO;ΔrG∘(1)\mathrm{PbO}_{2}+\mathrm{Pb} \rightarrow 2 \mathrm{PbO} ; \Delta_{\mathrm{r}} \mathrm{G}^{\circ}(1)
SnO2+Sn→2SnO;ΔrG∘(2)\mathrm{SnO}_{2}+\mathrm{Sn} \rightarrow 2 \mathrm{SnO} ; \Delta_{\mathrm{r}} \mathrm{G}^{\circ}(2)
Identify the correct set from the following

Options

  1. AΔrG∘(1)<0;ΔrG∘(2)<0\Delta_{\mathrm{r}} \mathrm{G}^{\circ}(1)<0 ; \Delta_{\mathrm{r}} \mathrm{G}^{\circ}(2)<0
  2. BΔrG∘(1)>0;ΔrG∘(2)>0\Delta_{\mathrm{r}} \mathrm{G}^{\circ}(1)>0 ; \Delta_{\mathrm{r}} \mathrm{G}^{\circ}(2)>0
  3. CΔrG∘(1)<0;ΔrG∘(2)>0\Delta_{\mathrm{r}} \mathrm{G}^{\circ}(1)<0 ; \Delta_{\mathrm{r}} \mathrm{G}^{\circ}(2)>0
  4. DΔrG∘(1)>0;ΔrG∘(2)<0\Delta_{\mathrm{r}} \mathrm{G}^{\circ}(1)>0 ; \Delta_{\mathrm{r}} \mathrm{G}^{\circ}(2)<0

Correct answer

C. ΔrG∘(1)<0;ΔrG∘(2)>0\Delta_{\mathrm{r}} \mathrm{G}^{\circ}(1)<0 ; \Delta_{\mathrm{r}} \mathrm{G}^{\circ}(2)>0

Step-by-step solution

The stability of oxidation states in Group 14 is governed by the inert pair effect, which increases down the group.
For Lead (PbPb), the +2+2 oxidation state is more stable than the +4+4 state (Pb2+>Pb4+Pb^{2+} > Pb^{4+}).
In the reaction PbO2+Pb→2PbOPbO_2 + Pb \rightarrow 2PbO, Pb4+Pb^{4+} is being reduced to Pb2+Pb^{2+} and Pb0Pb^0 is being oxidized to Pb2+Pb^{2+}. Since the product contains the more stable oxidation state, the reaction is spontaneous, meaning ΔrG∘(1)<0\Delta_r G^\circ(1) < 0.
For Tin (SnSn), the +4+4 oxidation state is more stable than the +2+2 state (Sn4+>Sn2+Sn^{4+} > Sn^{2+}).
In the reaction SnO2+Sn→2SnOSnO_2 + Sn \rightarrow 2SnO, the stable Sn4+Sn^{4+} is being converted into the less stable Sn2+Sn^{2+}. This process is non-spontaneous, meaning ΔrG∘(2)>0\Delta_r G^\circ(2) > 0.
Thus, the correct set is ΔrG∘(1)<0\Delta_r G^\circ(1) < 0 and ΔrG∘(2)>0\Delta_r G^\circ(2) > 0.
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