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JEE Main 202622 JanuaryEvening Shift
Exam
JEE Main
Year
2026
Date
22 January
Shift
Evening Shift
Subject
Chemistry
Chapter
p Block Elements (Group 13 & 14)

JEE Main 2026 · 22 January · Evening Shift · Chemistry · p Block Elements (Group 13 & 14)

Given below are two statements : Statement I : Elements ' X ' and '...

Given below are two statements :
Statement I: Elements ' XX ' and ' YY ' are the most and least electronegative elements, respectively among N,As,SbandP.Thenatureoftheoxides\mathrm{N}, \mathrm{As}, \mathrm{Sb} and P. The nature of the oxides\mathrm{X}_{2} \mathrm{O}_{3}andand\mathrm{Y}_{2} \mathrm{O}_{3}isacidicandamphoteric,respectively.<br><b>StatementII</b>:is acidic and amphoteric, respectively. <br> <b>Statement II</b> :\quad \mathrm{BCl}_{3}iscovalentinnatureandgetshydrolysedinwater.Itproduces[B(OH)4]−is covalent in nature and gets hydrolysed in water. It produces \left[\mathrm{B}(\mathrm{OH})_{4}\right]^{-} and \left[\mathrm{B}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{3+} in aqueous medium.
In the light of the above statements, choose the correct answer from the options given below :

Options

  1. ABoth Statement I and Statement II are false
  2. BBoth Statement I and Statement II are true
  3. CStatement I is true but Statement II is false
  4. DStatement I is false but Statement II is true

Correct answer

C. Statement I is true but Statement II is false

Step-by-step solution

For Statement I:
Among N, As, Sb, P, the electronegativity order is N > P > As > Sb. Thus X = N (most electronegative) and Y = Sb (least electronegative). N2O3N_2O_3 is acidic (forms HNO₂ with water)andSb2O3and Sb_2O_3 is amphoteric (reacts with both acids and bases).
Statement I is true.
For Statement II:
While BCl3BCl_3 is covalent and hydrolyzes in water to form B(OH)3B(OH)_3, the hydrolysis products are incorrect. In neutral aqueous medium, B(OH)3B(OH)_3 is formed. The tetrahedral [B(OH)4]−[B(OH)_4]^- forms only in basic conditions, and boron does not form [B(H2O)6]3+[B(H_2O)_6]^{3+} (boron is not a typical transition metal).
Statement II is false.
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