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JEE Main 20253 AprilMorning Shift
Exam
JEE Main
Year
2025
Date
3 April
Shift
Morning Shift
Subject
Chemistry
Chapter
p Block Elements (Group 15, 16, 17 & 18)

JEE Main 2025 · 3 April · Morning Shift · Chemistry · p Block Elements (Group 15, 16, 17 & 18)

Given below are two statements Statement I : The N-N single bond is...

Given below are two statements
Statement I : The N-N single bond is weaker and longer than that of P−P\mathrm{P}-\mathrm{P} single bond
Statement II : Compounds of group 15 elements in +3 oxidation states readily undergo disproportionation reactions.
In the light of above statements, choose the correct answer from the options given below

Options

  1. AStatement I is true but statement II is false
  2. BBoth statement I and statement II are false
  3. CStatement I is false but statement II is true
  4. DBoth statement I and statement II are true

Correct answer

B. Both statement I and statement II are false

Step-by-step solution

N¨−N¨\ddot{\mathrm{N}}-\ddot{\mathrm{N}} single bond weaker than P¨−P¨\ddot{\mathrm{P}}-\ddot{\mathrm{P}} due to more ℓp−ℓp\ell \mathrm{p}-\ell \mathrm{p} repulsion.
Bond length ⇒dp−p>dN−N(size⁡↑\Rightarrow d_{p-p} \gt d_{N-N}(\operatorname{size} \uparrow, B.L. ↑)\uparrow)
In group 15 elements only N \& P show disproportionation in +3 oxidation state, As, Sb \& Bi have almost inert for disproportionation in +3 oxidation state.
So both statements are false.
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