JEE Main202313 Apr 2023Evening ShiftChemistryp Block Elements (Group 15, 16, 17 & 18)Actual
The correct group of halide ions which can be oxidised by oxygen in acidic medium is
Options
- ABr – and I – only
- BBr – only
- CI – only
- DCl –   ,   Br – and I – only
Correct answer
C. I – only
Step-by-step solution
Fluorine oxidises water to oxygen whereas chlorine & bromine react with water to form corresponding HX   &   HOX acids. 2 F 2 + 2 H 2 O → 4 HF + O 2 Cl 2 + H 2 O → HCl + HOCl The reaction of I 2 with water is nonspontaneous. In fact I – can be oxidised by oxygen in acidic medium. It is why the I – in nature is not present in that much amount as other halides are present in nature.