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JEE Main202329 Jan 2023Morning ShiftChemistryp Block Elements (Group 15, 16, 17 & 18)Actual

“ A ” obtained by Ostwald's method involving air oxidation of NH 3 , upon further air oxidation produces “ B ”. “ B ” on hydration forms an oxoacid of Nitrogen along with evolution of “ A ”. The oxoacid also produces “ A ” and gives positive brown ring test

Options

  1. ANO 2 ,   N 2 O 5
  2. BNO 2 ,   N 2 O 4
  3. CNO ,   NO 2
  4. DN 2 O 3 ,   NO 2

Correct answer

C. NO ,   NO 2

Step-by-step solution

Ostwald's method is based upon catalytic oxidation of NH 3 by atmospheric oxygen. 4 NH 3   ( g )   + 5 O 2   ( g )   → 500 K ,   9   bar Pt / Rh   gauge   catalyst   4 NO   ( g )   ( A ) + 6 H 2 O   ( g ) Nitric oxide thus formed combines with oxygen giving NO 2 . 2 NO   ( g )   + O 2   ( g )   ⇌   2 NO 2   ( g ) ( B ) Nitrogen dioxide so formed, dissolves in water to give HNO 3 . 3 NO 2   ( g )   + &

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