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JEE Main 202325 JanuaryMorning Shift
Exam
JEE Main
Year
2023
Date
25 January
Shift
Morning Shift
Subject
Chemistry
Chapter
p Block Elements (Group 15, 16, 17 & 18)

JEE Main 2023 · 25 January · Morning Shift · Chemistry · p Block Elements (Group 15, 16, 17 & 18)

Compound A reacts with NH _ 4 Cl and forms a compound B. Compound B...

Compound A reacts with NH4Cl{NH}_{4}Cl and forms a compound B. Compound B reacts with H2O{H}_{2}O and excess of CO2{CO}_{2} to form compound C which on passing through or reaction with saturated NaCl solution forms sodium hydrogen carbonate. Compound A. B and C, are respectively.

Options

  1. ACaCl2,NH3,NH4HCO3{CaCl}_{2}, {NH}_{3}, {NH}_{4}{HCO}_{3}
  2. B{CaCl}_{2}, {NH}_{4}^{+}, {\left({NH}_{4}\right)}_{2}{CO}_{3}
  3. CCa(OH)2,NH3,NH4HCO3Ca ( OH{)}_{2}, {NH}_{3}, {NH}_{4}{HCO}_{3}
  4. DCa ( OH{)}_{2}, {NH}_{4}^{+}, {\left({NH}_{4}\right)}_{2}{CO}_{3}

Correct answer

C. Ca(OH)2,NH3,NH4HCO3Ca ( OH{)}_{2}, {NH}_{3}, {NH}_{4}{HCO}_{3}

Step-by-step solution

When calcium hydroxide is reacted with crystals of ammonium chloride, the products formed as calcium chloride, ammonia and water.

Ca(OH)2+NH4Cl→CaCl2+2NH3+2H2OCa ( OH{)}_{2} + {NH}_{4}Cl \to {CaCl}_{2} + 2{NH}_{3} + 2{H}_{2}O

When ammonia is reacted with water and excess carbon dioxide, it forms ammonium hydrogen carbonate which on passing through with saturated NaCl solution forms hydrogen carbonate.

NH3+H2O+CO2→NH4HCO3{NH}_{3} + {H}_{2}O + {CO}_{2} \to {NH}_{4}{HCO}_{3}

NH4HCO3+NaCl→NaHCO3↓+NH4Cl{NH}_{4}{HCO}_{3} + NaCl \to {NaHCO}_{3} ↓ + {NH}_{4}Cl

So, the compound A, B, and C are Ca(OH)2,NH3,NH4HCO3Ca ( OH{)}_{2}, N{H}_{3}, N{H}_{4}HC{O}_{3} respectively.

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