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JEE Main 202228 JulyMorning Shift
Exam
JEE Main
Year
2022
Date
28 July
Shift
Morning Shift
Subject
Chemistry
Chapter
p Block Elements (Group 15, 16, 17 & 18)

JEE Main 2022 · 28 July · Morning Shift · Chemistry · p Block Elements (Group 15, 16, 17 & 18)

Match List-I with List-II, match the gas evolved during each...

Match List-I with List-II, match the gas evolved during each reaction.

List-I List-II
A (NH4)2Cr2O7⟶Δ{\left({NH}_{4}\right)}_{2}{Cr}_{2}{O}_{7}\overset{\Delta}{⟶} I H2{H}_{2}
B KMnO4+HCl→{KMnO}_{4} + HCl \to II N2{N}_{2}
C Al+NaOH+H2O→Al + NaOH + {H}_{2}O \to III O2{O}_{2}
D NaNO3⟶Δ{NaNO}_{3}\overset{\Delta}{⟶} IV Cl2{Cl}_{2}

Choose the correct answer from the options given below

Options

  1. AA−II,B−III,C−I,D−IVA - II, B - III, C - I, D - IV
  2. BA−III,B−I,C−IV,D−IIA - III, B - I, C - IV, D - II
  3. CA−II,B−IV,C−I,D−IIIA - II, B - IV, C - I, D - III
  4. DA−III,B−IV,C−I,D−IIA - III, B - IV, C - I, D - II

Correct answer

C. A−II,B−IV,C−I,D−IIIA - II, B - IV, C - I, D - III

Step-by-step solution

Thermal decomposition of ammonium dichromate (NH4)2Cr2O7{( {NH}_{4} )}_{2}{Cr}_{2}{O}_{7} on heating gives N2,Cr2O3{N}_{2}, {Cr}_{2}{O}_{3} and H2O{H}_{2}O as follows:

(NH4)2Cr2O7→∆N2+Cr2O3+4H2O{\left({NH}_{4}\right)}_{2}{Cr}_{2}{O}_{7}\overset{∆}{\to}{N}_{2} + {Cr}_{2}{O}_{3} + 4{H}_{2}O

2KMnO4(s)+16HCl(aq)→2KCl(aq)+2MnCl2(aq)+8H2O(l)+5Cl2(g)2{KMnO}_{4\left(s\right)} + 16HCl\left(aq\right) \to 2KCl\left(aq\right) + 2{MnCl}_{2\left(aq\right)} + 8{H}_{2}O\left(l\right) + 5{Cl}_{2\left(g\right)}

The reaction of Aluminium with Sodium hydroxide (Al+NaOH)( Al + NaOH ) gives a salt and Hydrogen gas.

2Al(s)+2NaOH(l)+6H2O(l)→2Na[Al(OH)4](s)+3H2(l)2Al\left(s\right) + 2NaOH\left(l\right) + 6{H}_{2}O\left(l\right) \to 2Na\left[Al{\left(OH\right)}_{4}\right]\left(s\right) + 3{H}_{2}\left(l\right)

On heating sodium nitrate it undergoes decomposition reaction and liberates oxygen and convert into sodium nitrite.

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