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JEE Main 202226 JulyEvening Shift
Exam
JEE Main
Year
2022
Date
26 July
Shift
Evening Shift
Subject
Chemistry
Chapter
p Block Elements (Group 15, 16, 17 & 18)

JEE Main 2022 · 26 July · Evening Shift · Chemistry · p Block Elements (Group 15, 16, 17 & 18)

The number of non-ionisable protons present in the product B...

The number of non-ionisable protons present in the product BB obtained from the following reaction is___C2H5OH+PCl3→C2H5Cl+A{C}_{2}{H}_{5}OH + {PCl}_{3} \to {C}_{2}{H}_{5}Cl + A

A+PCl3→BA + {PCl}_{3} \to B

The number of non-ionisable protons present in the product B obtained from the following reaction is___ C _ 2 H _ 5 OH

Correct answer

0

Step-by-step solution

C2H5OH+PCl3⟶C2H5Cl+H3PO3{C}_{2}{H}_{5}OH + {PCl}_{3} ⟶ {C}_{2}{H}_{5}Cl + {H}_{3}{PO}_{3}

H3PO3+PCl3⟶H4P2O5+HCl{H}_{3}{PO}_{3} + {PCl}_{3} ⟶ {H}_{4}{P}_{2}{O}_{5} + HCl

A is H3PO3{H}_{3}{PO}_{3}(Phosphorous acid)

The basicity of A is two

B is H4P2O5{H}_{4}{P}_{2}{O}_{5}(Pyrophosphorous acid)

Structure of H4P2O5{H}_{4}{P}_{2}{O}_{5} is as given below

The number of non-ionisable protons present in the product B obtained from the following reaction is___ C _ 2 H _ 5 OH

Hydrogen which are directly attached to the phosphorous in the above structure are non-ionisable.

The Number of non-ionisable hydrogen atoms are two in the above structure.

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