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JEE Main 202226 JuneMorning Shift
Exam
JEE Main
Year
2022
Date
26 June
Shift
Morning Shift
Subject
Chemistry
Chapter
p Block Elements (Group 15, 16, 17 & 18)

JEE Main 2022 · 26 June · Morning Shift · Chemistry · p Block Elements (Group 15, 16, 17 & 18)

Consider the following reaction : 2 HSO _ 4 ^ -...

Consider the following reaction :

2HSO4−(aq)(1)Electrolysis(2)Hydrolysis2HSO4−+2H++A2{HSO}_{4}^{-}\left(aq\right)\dfrac{\left(1\right)Electrolysis}{\left(2\right)Hydrolysis}2{HSO}_{4}^{-} + 2{H}^{+} + A

The dihedral angle in product AA in its solid phase at 110K110K is

Consider the following reaction : 2 HSO _ 4 ^ - (aq)((1)Electrolysis)/((2)Hydrolysis)2 HSO _ 4 ^ - + 2 H ^ + + A The

Options

  1. A104°104 °
  2. B111.5°111 . 5 °
  3. C90.2°90 . 2 °
  4. D111.0°111 . 0 °

Correct answer

C. 90.2°90 . 2 °

Step-by-step solution

Peroxodisulphate, obtained by electrolytic oxidation of acidified sulphate solutions at high current density, on hydrolysis yields hydrogen peroxide.

2HSO4−(aq)⟶ElectrolysisHO3SOOSO3H(aq)→Hydrolysis2HSO4−(aq)+2H+(aq)+H2O2(aq)2{HSO}_{4}^{-} ( aq ) \overset{Electrolysis}{⟶}{HO}_{3}{SOOSO}_{3}H ( aq ) \overset{Hydrolysis}{\to}2{HSO}_{4}^{-} ( aq ) + 2{H}^{+} ( aq ) + {H}_{2}{O}_{2} ( aq )

Hydrogen peroxide has a non-planar structure. The molecular dimensions in the gas phase and solid phase are shown

Consider the following reaction : 2 HSO _ 4 ^ - (aq)((1)Electrolysis)/((2)Hydrolysis)2 HSO _ 4 ^ - + 2 H ^ + + A The

H2O2{H}_{2}{O}_{2} structure in gas phase, dihedral angle is 111.5°111 . 5 °.

H2O2{H}_{2}{O}_{2} structure in solid phase at 110K110K, dihedral angle is 90.2°90 . 2 °.

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