Most Important Selected Qs for JEE AdvancedChemistryThermodynamics (C)
On the basis of the following graph ( P - V ) graph, choose the correct statements.
Options
- AThe entropy change for the over all process is zero
- BFor the over all process H E
- CTotal work done, W = q
- DTotal work =-620.77 ~J
Correct answer
D. Total work =-620.77 ~J
Step-by-step solution
Thus it is a cyclic process. Hence, E=0, H=0, S=0 and gathered E = q + w (1^ st law ) 0= q + w gathered or q=-w aligned & Total work done = W _ A B + W _ B C + W _ C A & w =- P ( V _ B - V _ A )+0+2.303 nRT V _ C V _ A & =-(40-20)+0+2.303 1 0.082 V _ C V _ A & =-6.13 litre-atmosphere & =-620.77 ~J aligned