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JEE Main 202117 MarchMorning Shift
Exam
JEE Main
Year
2021
Date
17 March
Shift
Morning Shift
Subject
Chemistry
Chapter
p Block Elements (Group 15, 16, 17 & 18)

JEE Main 2021 · 17 March · Morning Shift · Chemistry · p Block Elements (Group 15, 16, 17 & 18)

The reaction of white phosphorus on boiling with alkali in inert...

The reaction of white phosphorus on boiling with alkali in inert atmosphere resulted in the formation of product A.A . The reaction 1mol1mol of AA with excess of AgNO3{AgNO}_{3} in aqueous medium gives ________ mole(s)ofAg.of Ag . (Round off to the Nearest Integer).

Correct answer

0

Step-by-step solution

P4+3OH−+3H2O→PH3+3H2PO2−(A){P}_{4} + 3{OH}^{-} + 3{H}_{2}O \to {PH}_{3} + \mathop{3{H}_{2}{PO}_{2}^{-}}_{\left(A\right)}

H2PO2−1mole+4Ag+excess+2H2O→H3PO4+4Ag+3H+4mole\mathop{{H}_{2}{PO}_{2}^{-}}_{1\text{mole}} + \mathop{4{Ag}^{+}}_{\text{excess}} + 2{H}_{2}O \to \mathop{{H}_{3}{PO}_{4} + 4Ag + 3{H}^{+}}_{4\text{mole}}

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