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JEE Main 201912 JanuaryMorning Shift
Exam
JEE Main
Year
2019
Date
12 January
Shift
Morning Shift
Subject
Chemistry
Chapter
p Block Elements (Group 15, 16, 17 & 18)

JEE Main 2019 · 12 January · Morning Shift · Chemistry · p Block Elements (Group 15, 16, 17 & 18)

Iodine reacts with concentrated HN O _ 3 to yield Y along with...

Iodine reacts with concentrated HNO3HN{O}_{3} to yield YY along with other products. The oxidation state of iodine in YY , is:

Options

  1. A11
  2. B55
  3. C33
  4. D77

Correct answer

B. 55

Step-by-step solution

I2+10HNO3→2HIO3+10NO2+4H2O{I}_{2} + 10HN{O}_{3} \to 2HI{O}_{3} + 10N{O}_{2} + 4{H}_{2}O

Iodine gets oxidized to IO3−I{O}_{3}^{-} when it reacts with an oxidizing agent \left(HN{O}_{3}\right) .TheoxidationnumberofThe oxidation number ofIinproductwillbe<br/><br/>Oxidation:in product will be<br /><br />Oxidation:{I}_{2} - I{O}_{3}^{-}<br/><br/><br /><br />- 1 = x + 3 \times \left(- 2\right)

−1=x−6- 1 = x - 6

x = - 1 + 6 = + 5

Reduction: concentrated HNO3 gives NO2.

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