JEE Main2015Chemistryp Block Elements (Group 15, 16, 17 & 18)Actual
Chlorine water on standing loses its color and forms:
Options
- AH O C l a n d H O C l 2
- BH C l o n l y
- CH C l a n d H C l O 2
- DH C l a n d H O C l
Correct answer
D. H C l a n d H O C l
Step-by-step solution
Chlorine water loses it's yellow color on standing in sunlight because it forms mixture of hypochlorous acid ( HOCl ) and hydrochloric acid HCl . C l 2 ( g ) Is soluble in H 2 O and form chlorine water, in presence of sunlight as C l 2 g + H 2 O → H C l + H O C l This is a disproportionation reaction., where chlorine changes it's oxidation state from zero in Cl 2 to -1 in HCl and +1 in HOCl . Hypochlorous acid formed in this reaction gives nascent oxygen which is responsible for bleaching action