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JEE Main 201511 AprilOnline
Exam
JEE Main
Year
2015
Date
11 April
Mode
Online
Subject
Chemistry
Chapter
p Block Elements (Group 15, 16, 17 & 18)

JEE Main 2015 · 11 April · Online · Chemistry · p Block Elements (Group 15, 16, 17 & 18)

Chlorine water on standing loses its color and forms:

Chlorine water on standing loses its color and forms:

Options

  1. AHOClandHOCl2HOClandHOC{l}_{2}
  2. BHClonlyHClonly
  3. CHClandHClO2HClandHCl{O}_{2}
  4. DHClandHOClHClandHOCl

Correct answer

D. HClandHOClHClandHOCl

Step-by-step solution

Chlorine water loses it's yellow color on standing in sunlight because it forms mixture of hypochlorous acid (HOCl)( HOCl ) and hydrochloric acid \left(HCl\right).</p><p>.</p><p>C{l}_{2} ( g )IssolubleinIs soluble in{H}_{2}Oandformchlorinewater,inpresenceofsunlightas<br/><br/>and form chlorine water, in presence of sunlight as<br /><br />C{l}_{2}\left(g\right) + {H}_{2}O \to HCl + HOCl</p><p>Thisisadisproportionationreaction.,wherechlorinechangesit′soxidationstatefromzeroin</p><p>This is a disproportionation reaction., where chlorine changes it's oxidation state from zero in{Cl}_{2}to−1into -1 inHCland+1inand +1 inHOCl. Hypochlorous acid formed in this reaction gives nascent oxygen which is responsible for bleaching action

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