Most Important Selected Qs for JEE AdvancedChemistryp Block Elements (Group 15, 16, 17 & 18)
Paragraph: In oxoacids of phosphorus, P is tetrahedrally surrounded by other atoms. All these acids contain one P = O and P - OH bond. The oxoacids in which phosphorus has lower oxidation state (less than +5 ) contain, in addition to P = O and P - OH bonds, either P - P (e.g., in H ₄ P ₂ O ₆ ) or P - H (e.g., in . H ₃ PO ₂ ) bonds but not both. These acids in +3 oxidation state of phosphorus tend to disproportionate
Options
- ACu
- BCu ₂ O
- CCuO
- DCu ₂ H ₂
Correct answer
D. Cu ₂ H ₂
Step-by-step solution
Copper sulphate when reacts with hypophosphorus acid, gets reduced to cuprous hydride. 4 CuSO ₄+3 H ₃ PO ₂+6 H ₂ O 2 Cu ₂ H ₂+3 H ₃ PO ₄+4 H ₂ SO ₄