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Most Important Selected Qs for JEE AdvancedChemistryp Block Elements (Group 15, 16, 17 & 18)

Paragraph: In oxoacids of phosphorus, P is tetrahedrally surrounded by other atoms. All these acids contain one P = O and P - OH bond. The oxoacids in which phosphorus has lower oxidation state (less than +5) contain, in addition to P = O and P - OH bonds, either P - P (e.g., in H ₄ P ₂ O ₆ ) or P - H (e.g., in . H ₃ PO ₂ ) bonds but not both. These acids in +3 oxidation state of phosphorus tend to disproportionate t

Options

  1. ABa ( OH )₂, PH ₃, Ba ( H ₂ PO ₂ )₂, H ₃ PO ₂, BaSO ₄
  2. BCa ( OH )₂, P ₂ H ₄, Ba ( H ₂ PO ₂ )₃, H ₃ PO ₂, CaSO ₄
  3. CBa ( OH )₂, PH ₃, Ba ( H ₂ PO ₂ )₃, H ₃ PO ₃, BaSO ₄
  4. DBa ( OH )₂, P ₂ H ₄, Ba ( H ₂ PO ₂ )₂, H ₃ PO ₂, BaSO ₄

Correct answer

A. Ba ( OH )₂, PH ₃, Ba ( H ₂ PO ₂ )₂, H ₃ PO ₂, BaSO ₄

Step-by-step solution

(J) 3 Ba ( OH )₂ +2 P ₄+6 H ₂ O (L) 3 Ba ( H ₂ PO ₂ )₂ + (K) 2 PH ₃ (L) Ba ( H ₂ PO ₂ )₂ + H ₂ SO ₄ (N) BaSO ₄ + (M) 2 H ₃ PO ₂ gives apple green colour in the flame

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