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JEE Main 202311 AprilMorning Shift
Exam
JEE Main
Year
2023
Date
11 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Solid State

JEE Main 2023 · 11 April · Morning Shift · Chemistry · Solid State

An atomic substance A of molar mass 12g mol ^ – 1 has a cubic...

An atomic substance A of molar mass 12gmol–112g{mol}^{– 1}has a cubic crystal structure with edge length of 300pm300pm. The no. of atoms present in one unit cell of A is

(Nearest integer)

Given the density of A is 3.0gmm−13 . 0gm{m}^{- 1} and NAA=6.02×1023mol−1{NA}_{A} = 6 . 02 \times {10}^{23}{mol}^{- 1}

Correct answer

0

Step-by-step solution

The density of crystal can be calculated as follows,

ρ=Z×MNA×a3ρ = \dfrac{Z \times M}{{N}_{A} \times {a}^{3}}

ρ=ρ =density of the unit cell

Z=Z =Effective atomic number

M=M =Molar mass

NA={N}_{A} =Avogadro's number

a=a =Edge length of the unit cell

3=Z×126.02×1023×(3)3×10−243 = \dfrac{Z \times 12}{6 . 02 \times {10}^{23} \times ( 3{)}^{3} \times {10}^{- 24}}

Z=6.02×10−1×274=4Z = \dfrac{6 . 02 \times {10}^{- 1} \times 27}{4} = 4

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